En particulier, le ligand L du motif de formule (I) de la prsente invention peut tre un ligand di-, tri- ou ttra- carboxylate choisi dans le groupe comprenant : C 2 H 2 ( CO 2 " ) 2 (fumarate), C 2 H 4 ( CO 2 " ) 2 In particular, the ligand L of the unit of formula (I) of the present invention may be a di-, tri- or tetracarboxylate ligand chosen from the group comprising: C 2 H 2 (CO 2 " ) 2 (fumarate), C 2 H 4 (CO 2 " ) 2 (succinate), C 3 H 6 ( CO 2 " ) 2 (glutarate), C 4 H 4 ( CO 2 " ) 2 (succinate), C 3 H 6 (CO 2 " ) 2 (glutarate), C 4 H 4 (CO 2 " ) 2 (muconate), C 4 H 8 (CO 2 ~ ) 2 (adipate), C 7 H 14 (CO 2 ^ ) 2 (azelate), C 5 H 3 S (CO 2 " ) 2 (2,5-thiophnedicarboxylate) , C 6 H 4 ( CO 2 " ) 2 (trphtalate), C 6 H 2 N 2 ( CO 2 " ) 2 (2,5-pyrazine dicarboxylate) , C 10 H 6 ( CO 2 " ) 2 (naphtalne-2, 6- dicarboxylate) , C 12 H 8 ( CO 2 " ) 2 (biphnyle-4,4 ' - dicarboxylate ) , C 12 H 8 N 2 ( CO 2 " ) 2 ( azobenznedicarboxylate ) , C 6 H 3 (CO 2 -J 3 (benzne-l,2,4-tricarboxylate) , C 6 H 3 (CO 2 " ) 3 (benzne-l,3,5-tricarboxylate) , C 24 H 15 (CO 2 " ) 3 (benzne- 1,3, 5-tribenzoate) , C 6 H 2 (CO 2 " ) 4 (benzne-1,2 ,4,5- ttracarboxylate, C 10 H 4 (CO 2 -J 4 (naphtalne-2 , 3,6,7 - ttracarboxylate) , C 10 H 4 ( CO 2 " ) 4 (naphtalne-1,4,5,8- ttracarboxylate) , C 12 H 6 ( CO 2 " ) 4 (biphnyl-3,5,3 ' ,5 ' - ttracarboxylate), et les analogues modifis choisis dans le groupe comprenant le 2-aminotrphtalate, le 2- nitrotrphtalate, le 2 -mthyl trphtalate, le 2- chlorotrphtalate, le 2-bromotrphtalate, le 2,5- dihydroxotrphtalate , le ttrafluorotrphtalate, le ttramthyltrphtalate , le dimthyl-4,4'- biphnydicarboxylate, le ttramthyl-4,4 '- biphnydicarboxylate, le dicarboxy-4,4 '- biphnydicarboxylate, le 2,5-pyrazyne dicarboxylate
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